(N,N,N′,N′-Tetramethylethylenediamine-κN)bis(2,4,6-trimethylphenolato-κO)germanium(II)

The Ultrafast Structural Pathway of Charge Transfer in Tetramethylethylenediamine

n-Butyllithium/N,N,N',N'-tetramethylethylenediamine-mediated ortholithiations of aryl oxazolines: substrate-dependent mechanisms.

n-Butyllithium/N,N,N',N'-tetramethylethylenediamine-mediated ortholithiations of aryloxazolines are described. Methyl substituents on the aryloxazoline and substituents at the meta position of the arenes (methoxy, oxazolinyl, and fluoro) influence the rates and the mechanisms. Monomer- and dimer-based reactions are implicated. Density functional calculations probe details of the mechanism and s...

An ion pair scandium hydride supported by a dianionic (NNNN)-type macrocycle ligand.

A scandium hydride supported by a (NNNN)-type macrocycle consists of a trinuclear cation and a trinuclear anion. The anion shows significantly higher reactivity.

Ultrafast structural dynamics in Rydberg excited N,N,N0,N0-tetramethylethylenediamine: conformation dependent electron lone pair interaction and charge delocalization†

Two nitrogen atoms and a flexible carbon skeleton make N,N,N0,N0-tetramethylethylenediamine (TMEDA) an important model system to study the interplay of conformeric motions and charge delocalization. Ionization of one of the nitrogen atoms generates a localized charge that may (partially) transfer to the other nitrogen. The structural motions, conformation dependent electron lone pair interactio...

[η5-2,3-Bis(trimethylsilyl)-2,3-dicarba-nido-hexaborane(2−)]chlorido(N,N,N′,N′-tetramethylethylenediamine)dysprosium(III)

The structure of the title compound, [Dy(C(8)H(22)B(4)Si(2))Cl(C(6)H(16)N(2))], reveals that a center of symmetry exists within the dimeric half-sandwich units. Within each half-sandwich, the Dy(III) ion is coordinated by the five-membered ring of the carborane, tetramethylethyl-enediamine and the chloride ion.